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Structure of ionic liquids on the basis of imidazole and their mixtures with water
Authors:S. V. Troshenkova  E. S. Sashina  N. P. Novoselov  K. -F. Arndt  S. Jankowsky
Affiliation:(1) School of Chemical Engineering, Hefei University of Technology, 230009 Hefei, People’s Republic of China;(2) Department of Chemistry and Life Sciences, West Anhui University, Lu’an, People’s Republic of China
Abstract:
1-Ethyl-3-methylimidazolium acetate absorbs up to 27% of water from air at room temperature with liberation of a large amount of heat, 11 kJ mol−1. Ions of the ionic liquid do not enter into chemical reaction with water but form a stable complex of ethylmethylimidazolium acetate with 12H2O molecules (EMIA·12H2O).
Keywords:
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