Alkali metal 2-(1-adamantyl)ethynethiolates: Synthesis and reactions with electrophilic reagents |
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| Authors: | M. L. Petrov A. A. Shchipalkin V. A. Kuznetsov B. N. Viktorov |
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| Affiliation: | 1.St. Petersburg State Institute of Technology,St. Petersburg,Russia |
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| Abstract: | ![]()
Treatment of ethyl 2-[1-(1-admantyl)ethylidene]hydrazine-1-carboxylate with thionyl chloride gave 4-(1-adamantyl)-1,2,3-thiadiazole which readily underwent decomposition by the action of strong bases with formation of alkali metal 2-(1-adamantyl)ethynethiolates. The latter were brought into reactions with proton donors and benzyl halides. |
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