| 2，6-双(1-苯基苯并咪唑-2-)吡啶铱(Ⅲ)配合物的合成、晶体结构和发光性质 |
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| 引用本文： | 刘生桂,陈自卢,苏文义,潘荣楷,石晓波.2，6-双(1-苯基苯并咪唑-2-)吡啶铱(Ⅲ)配合物的合成、晶体结构和发光性质[J].无机化学学报,2013,29(2):403-408. |
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| 作者姓名： | 刘生桂 陈自卢 苏文义 潘荣楷 石晓波 |
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| 作者单位： | 1. 湛江师范学院化学科学与技术学院,广东高校新材料工程与技术研发中心,湛江524048
2. 广西师范大学化学化工学院,桂林,541004 |
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| 摘 要： | 苯基取代2,6-双苯并咪唑吡啶的2个NH的氢原子生成了2,6-双(1-苯基苯并咪唑-2-)吡啶配体(bpbp)。180℃加热条件下,IrCl3.6H2O和2,6-双(1苯基苯并咪唑-2-)吡啶合成了1个新的阳离子型配合物Ir(bpbp)2](PF6)3,它的结构经元素分析、红外光谱、氢核磁共振、X射线单晶衍射证实。Ir(bpbp)2](PF6)3配合物属于单斜晶系,空间群P2/n,a=1.435 1(5)nm,b=1.094 1(5)nm,c=2.206 9(5)nm,β=99.832(5)°,V=3.414(2)nm3,Z=2。中心金属离子Ir(Ⅲ)和来自2个配体的6个N原子配位,形成八面体几何结构。该配合物在二氯甲烷中发出明亮的黄绿荧光。
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| 关 键 词： | 苯并咪唑 铱配合物 晶体结构 发光 |
Synthesis, Crystal Structure and Luminescent Properties of Iridium(Ⅲ) Complex Based on 2,6-Bis(1-phenylbenzimidazol-2-yl)pyridine |
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| LIU Sheng-Gui,CHEN Zi-Lu,SU Wen-Yi,PAN Rong-Kai and SHI Xiao-Bo.Synthesis, Crystal Structure and Luminescent Properties of Iridium(Ⅲ) Complex Based on 2,6-Bis(1-phenylbenzimidazol-2-yl)pyridine[J].Chinese Journal of Inorganic Chemistry,2013,29(2):403-408. |
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| Authors: | LIU Sheng-Gui CHEN Zi-Lu SU Wen-Yi PAN Rong-Kai and SHI Xiao-Bo |
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| Institution: | School of Chemistry Science and Technology, Zhanjiang Normal University, Development Center for New Materials Engineering and Technology in Universities of Guangdong, Zhanjiang, Guangdong 524048, China;School of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin, Guangxi 541004, China;School of Chemistry Science and Technology, Zhanjiang Normal University, Development Center for New Materials Engineering and Technology in Universities of Guangdong, Zhanjiang, Guangdong 524048, China;School of Chemistry Science and Technology, Zhanjiang Normal University, Development Center for New Materials Engineering and Technology in Universities of Guangdong, Zhanjiang, Guangdong 524048, China;School of Chemistry Science and Technology, Zhanjiang Normal University, Development Center for New Materials Engineering and Technology in Universities of Guangdong, Zhanjiang, Guangdong 524048, China |
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| Abstract: | |
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| Keywords: | benzimidazole iridium complex crystal structure luminescence |
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