Hydroxoiridium/Chiral Diene Complexes as Effective Catalysts for Asymmetric Annulation of α‐Oxo‐ and Iminocarboxamides with 1,3‐Dienes |
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| Authors: | Miyuki Hatano Dr. Takahiro Nishimura |
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| Affiliation: | Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606‐8502 (Japan) |
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| Abstract: | ![]()
The asymmetric [3+2] annulation of α‐oxo‐ and α‐iminocarboxamides with 1,3‐dienes catalyzed by hydroxoiridium/chiral diene complexes was realized, giving high yields of the corresponding γ‐lactams with high enantioselectivity. |
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| Keywords: | [3+2] annulation asymmetric synthesis carboxamides chiral diene iridium |
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