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香豆素-3-羧酸铒(Ⅲ)一维配位聚合物[Er(CCA)_3(H_2O)_2]_n·2nH_2O的溶剂热法合成、晶体结构及与牛血清白蛋白(BSA)的相互作用
引用本文:杨树平,韩立军,王大奇,潘燕,余志群,叶海燕.香豆素-3-羧酸铒(Ⅲ)一维配位聚合物[Er(CCA)_3(H_2O)_2]_n·2nH_2O的溶剂热法合成、晶体结构及与牛血清白蛋白(BSA)的相互作用[J].化学学报,2011,69(19):2319-2327.
作者姓名:杨树平  韩立军  王大奇  潘燕  余志群  叶海燕
作者单位:1. 淮海工学院化学工程学院,连云港,222005
2. 淮海工学院数理学院,连云港,222005
3. 聊城大学化学工程学院,聊城,252059
4. 北京大学医学部基础医学院药理系及国家天然仿生药物重点实验室,北京,100191
基金项目:国家自然科学基金(No.30901815); 淮海工学院自然科学基金(No.Z2009019)资助项目
摘    要:利用溶剂热法合成了一维配位聚合物Er(CCA)3(H2O)2]n·2nH2O(HCCA=香豆素-3-羧酸),通过元素分析和IR对配合物进行了表征,用X-射线单晶衍射技术测定了其晶体结构.标题配合物晶体属于单斜晶系,P21/c空间群:a=0.6310(1)nm,b=1.4165(2)nm,c=3.1731(3)nm;β...

关 键 词:铒(Ⅲ)配位聚合物  香豆素-3-羧酸  晶体结构  牛血清白蛋白  荧光光谱  溶剂热法

Solvothermal Synthesis,Crystal Structure of a 1D Coordination Polymer [Er(CCA)_3(H_2O)_2]_no2nH_2O(HCCA=Coumarin-3-Carboxylic Acid) and the Interaction between the Polymer and Bovine Serum Albumin(BSA)
Yang,Shuping,a Han,Lijunb Wang,Daqic Pan,Y, Yu,Zhiquna Ye,Haiyana.Solvothermal Synthesis,Crystal Structure of a 1D Coordination Polymer [Er(CCA)_3(H_2O)_2]_no2nH_2O(HCCA=Coumarin-3-Carboxylic Acid) and the Interaction between the Polymer and Bovine Serum Albumin(BSA)[J].Acta Chimica Sinica,2011,69(19):2319-2327.
Authors:Yang  Shuping  a Han  Lijunb Wang  Daqic Pan  Y  Yu  Zhiquna Ye  Haiyana
Institution:Yang,Shuping,a Han,Lijunb Wang,Daqic Pan,Yand Yu,Zhiquna Ye,Haiyana(a School of Chemical Engineering,Huaihai Institute of Technology,Lianyungang 222005)(b School of Mathematics and Science,Lianyungang 222005)(c School of Chemistry and Chemical Engineering,Liaocheng University,Liaocheng 252059) (d State Key Laboratory of Natural and Biomimetic Drugs,Department of Pharmacology,School of Basic Medical Sciences,Peking University and Institute of System Biomedicine,Peking Universi...
Abstract:
Keywords:erbium(III) coordination polymer  coumarin-3-carboxylic acid  crystal structure  bovine serum albumin(BSA)  fluorescence spectra  solvent-thermal method  
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