| 三腈基呋喃推拉型电荷转移分子的双光子吸收 |
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| 引用本文： | 古彦,钱鹰,周志强,崔一平.三腈基呋喃推拉型电荷转移分子的双光子吸收[J].化学学报,2011,69(20):2499-2504. |
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| 作者姓名： | 古彦 钱鹰 周志强 崔一平 |
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| 作者单位： | 1. 东南大学化学化工学院,南京,211189
2. 东南大学先进光子学中心,南京,210096 |
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| 基金项目： | 国家自然科学基金(No.61178057)资助项目 |
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| 摘 要： | 根据双光子吸收效应与分子之间＂构效＂关系,设计四种D-π-A推拉偶极型电荷转移分子,采用AM1方法计算出分子三阶极化率,筛选出具有潜在三阶非线性光学活性分子2-（3-腈基-（3-（4-（二甲胺基）苯乙烯基）-5,5-二甲环己基-2-烯）甲基）-5,5-二甲基呋喃-2-烯）丙二腈（CFM）.首次在温和条件下使酮羰基与TC...
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| 关 键 词： | 三阶极化率 Knoevenagel反应 双光子吸收 推拉型分子 |
Two-photon Absorption of a Push-pull Type Intramolecular Charge Transfer Molecule Including Tricyanofuran |
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| Ji,Yana Qian,Ying,a Zhou,Zhiqiangb Cui,Yipingb.Two-photon Absorption of a Push-pull Type Intramolecular Charge Transfer Molecule Including Tricyanofuran[J].Acta Chimica Sinica,2011,69(20):2499-2504. |
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| Authors: | Ji Yana Qian Ying a Zhou Zhiqiangb Cui Yipingb |
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| Institution: | Ji,Yana Qian,Ying,a Zhou,Zhiqiangb Cui,Yipingb(a School of Chemistry and Chemical Engineering,Southeast University,Nanjing 211189)(b Advanced Photonics Center,Nanjing 210096) |
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| Abstract: | |
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| Keywords: | three-order polarizability Knoevenagel reaction two-photon absorption push-pull type mole-cule |
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