| Synthesis, Crystal Structure and Luminescent Properties of [Zn（bipy）_2（H_2O）_4]·L·3H_2O |
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| 作者姓名： | 陈友存 沈菲 王彦 许军军 汪快兵 |
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| 作者单位： | Anhui Provincial Laboratory of Optoelectronic and Magnetism Functional Materials;School of Chemistry and Chemical Engineering;Anqing Normal University;State Key Laboratory of Coordination Chemistry;Nanjing University; |
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| 基金项目： | Supported by the National Natural Science Foundation of China (Nos. 20771006 and 20901004) |
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| 摘 要： | A novel coordination complex [Zn(bipy)2(H2O)4]·L·3H2O (1, bipy = 4,4'-bipyridine, LHNa = aniline-2,5-disulfonic acid monosodium salt) has been synthesized from LHNa by using hydrothermal method and structurally characterized. The result indicates that complex 1 belongs to the monoclinic system, space group P21/c with a = 20.392(3), b = 7.4052(12), c = 23.843(3) , β = 116.253(10)°, V = 3.2291(8) 3, Z = 4, Dc = 1.553 g·cm-3, μ = 0.962 mm-1, F(000) = 1568, and the final R = 0.0497 and wR = 0.1290. The complex 1 has a 0-D discrete structure, and generates an infinite 3-D network with the aid of O–H…O hydrogen bonds and π-π interactions.
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| 关 键 词： | 晶体结构 发光性能 合成 联吡啶 单斜晶系 离散结构 相互作用 H2O |
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