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Relations between mean amplitudes of vibration and corresponding internuclear distances : II. Bonded carbon-carbon distances |
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| Authors: | S. J. Cyvin |
| Affiliation: | Division of Physical Chemistry, The University of Trondheim, N-7034 Trondheim-NTH Norway Laboratory of Electron Diffraction, Department of Chemistry, Moscow State University, Moscow 117234 U.S.S.R. |
| Abstract: | The empirical relation u(CCbond) = −0.071856 + 0.124162 r − 0.028974 r2 was established from a statistical treatment of 57 electron diffraction measurements (1.2086 r 1.549, where r is the bond distance, and u is the mean amplitude of vibration; both in Å units). The agreement between observed and calculated u values is significantly improved when compared with the corresponding treatment of bonded and non-bonded CC distances taken together. |
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