An Efficient Synthesis of de novo Imidates via Aza-Claisen Rearrangements of N-Allyl Ynamides |
| |
| Authors: | Dekorver Kyle A North Troy D Hsung Richard P |
| |
| Institution: | Division of Pharmaceutical Sciences and Department of Chemistry, 777 Highland Avenue, Rennebohm Hall, University of Wisconsin, Madison, WI 53705. |
| |
| Abstract: | A novel thermal 3-aza-Claisen rearrangement of N-allyl ynamides for the synthesis of α-allyl imidates is described. Also, a sequential aza-Claisen, Pd-catalyzed Overman rearrangement is described for the synthesis of azapine-2-ones. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
