Mechanism of the Reaction of Xenon Tetraoxide with Hydrogen: A Photochemical Reaction |
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| Authors: | Aleinikov N. N. Vasil'ev G. K. Kashtanov S. A. Makarov E. F. Chernyshev Yu. A. |
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| Affiliation: | (1) Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia |
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| Abstract: | The dependence of the rate of a photochemical reaction of XeO4with H2on the concentrations of H2and the diluent gases He and CO2is studied at room temperature. The results are compared with the data for the dark reaction. A mechanism with the elementary energetic branched-chain reaction OH (v) + XeO4 OH + O + XeO3is proposed to explain the results of the study. |
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