A viscometric study of poly(methyl methacrylate) in 2-alkoxyethanols |
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Authors: | O. Quadrat L. Mrkvičková |
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Affiliation: | Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, 162 06 Prague 6 Czechoslovakia |
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Abstract: | θ-Conditions, the temperature coefficient of unperturbed dimensions of the macromolecules and the thermodynamic interaction parameters ψ and κ were determined for solutions of poly(methyl methacrylate) in 2-alkoxyethanols (methoxy, ethoxy and butoxy). The results for this series of solvents fit the data reported for other solvents and dln . The dependence of parameters ψ and κ exhibited deviations from the theoretical dependence, mainly near the limiting value ψ = 0.5. |
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