Thermodynamics of dimerization in solution as a rational tool for inducing nematic vs. smectic organizations in lanthanidomesogens |
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Authors: | Jensen Thomas B Terazzi Emmanuel Donnio Bertrand Guillon Daniel Piguet Claude |
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Affiliation: | Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, 30 quai E. Ansermet, CH-1211, Geneva 4, Switzerland. |
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Abstract: | The judicious tuning of simple thermodynamic parameters controlling dimerization processes in solution induces a rational switch between smectic and nematic organizations in thermotropic lanthanide-containing liquid crystals. |
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