Reactions of O2 --Containing Supramolecules with Alkyl Halides |
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| Authors: | I. V. Efimova A. I. Pomeshchenko I. A. Opeida |
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| Affiliation: | (1) Litvinenko Institute of Physical Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Donetsk, Ukraine |
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| Abstract: | Formation of O2--containing supramolecules generated from the system 18-crown-6-KO2 and electrochemically (tetraethylammonium superoxide) and the kinetics of the reactions of the generated O2- with alkyl halides in acetonitrile were studied conductometrically and UV-spectrophotometrically; the kinetic parameters of the processes were determined. The E2 mechanism was suggested for the reaction. |
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