| 过渡金属席夫碱配合物的稳定性及其杀菌活性 |
| |
| 引用本文： | 张建民,李瑞芳,刘树祥.过渡金属席夫碱配合物的稳定性及其杀菌活性[J].无机化学学报,1999,15(4):493-496. |
| |
| 作者姓名： | 张建民 李瑞芳 刘树祥 |
| |
| 作者单位： | 1. 曲阜师范大学生物系,曲阜,273165
2. 曲阜师范大学化学系,曲阜,273165 |
| |
| 摘 要： | 在25±0.1℃，I=0.1 mol·L-1 KNO3条件下，应用pH法测定了甲酰基甲酸缩氨基硫脲(A配体，缩写H2FFTSC)，甘氨酰甘氨酸(B配体，缩写HGG)的质子化常数，它们与锰(Ⅱ)、钴(Ⅱ)、镍(Ⅱ)、铜(Ⅱ)和锌(Ⅱ)的二元配合物以及过渡金属(Ⅱ)-甲酰基甲酸缩氨基硫脲-甘氨酰甘氨酸三元配合物稳定常数，讨论了过渡金属席夫碱配合物的杀菌活性与其稳定性之间的关系，对杀菌机理提出了一些看法。
|
| 关 键 词： | 过渡金属 席夫碱配合物 甘氨酰甘氨酸 配合物稳定性 杀菌活性 |
A RELATION BETWEEN STABILITY OF TRANSITION METAL SHIFF BASE COMPLEXES AND THEIR DISINFECTIVITY |
| |
| ZHANG Jian-Min,LI Rui-Fang and LIU Shu-Xiang.A RELATION BETWEEN STABILITY OF TRANSITION METAL SHIFF BASE COMPLEXES AND THEIR DISINFECTIVITY[J].Chinese Journal of Inorganic Chemistry,1999,15(4):493-496. |
| |
| Authors: | ZHANG Jian-Min LI Rui-Fang and LIU Shu-Xiang |
| |
| Institution: | Biology Department, Qufu Normal University, Qufu 273165,Chemistry Department, Qufu Normal University, Qufu 273165 and Chemistry Department, Qufu Normal University, Qufu 273165 |
| |
| Abstract: | = The protonation constants of formylformic acid thiosemicarbazone (A,
H\-2FFTSC) and glycylglycine (B, HGG) and stability constants of binary complexes formed they
with Mn(), Co(), Ni(), Cu() and Zn() and trinary complexes of M()FFTSCGG at 250.1 and in the
presence of 0.1 molL\ \{-1\} KNO\-3 were determined. The relation between the stability of
binary complexes of M()FFTSC and their disinfectivity and disinfection mechanism were
discussed.\=Z] |
| |
| Keywords: | Shiff base complexes transition metal glycylglycine stability of complex disinfectivity |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
