Magnetic properties and magnetocaloric effect in NdxLa1-xFe11.5Al1.5 compounds |
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Authors: | Wang Fang Wang Guang-Jun Sun Ji-Rong and Shen Bao-Gen |
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Institution: | State Key Laboratory of Magnetism, Institute of Physics and
Centre
for Condensed Matter Physics, \Chinese Academy of Sciences, Beijing 100190, China |
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Abstract: | Effects of Nd-doping on the magnetic properties and magnetocaloric
effects (MCEs) of Ndmagnetic properties,
NaZnmagnetic properties,
NaZn$_{13}$-type compounds, magnetic entropy changeProject supported
by the National Natural Science Foundation of China (Grant Nos
50571112 and 50731007), the National Basic Research Program of China
(Grant No 2006CB601101) and the Basic Research Program of Chinese
Academy of Science (Grant No
KJCX2-YW-W02s).7530S, 6540, 7550E, 0570FEffects of Nd-doping on the magnetic properties and magnetocaloric
effects (MCEs) of Nd$_{x}$La$_{1 - x}$Fe$_{11.5}$Al$_{1.5}$ have
been investigated. Substitution of Nd leads to a weakening of the
antiferromagnetic (AFM) coupling and an enhancement of the
ferromagnetic (FM) coupling. This in turn results in a complex
magnetic behaviour for Nd$_{0.2}$La$_{0.8}$Fe$_{11.5}$Al$_{1.5}$
characterized by the occurrence of two phase transitions at
$\sim$188\,K (PM--AFM) and $\sim $159\,K (AFM--FM). As a result, a
table-like MCE (9\,J/kg$\cdot$K) is found in a wide temperature
range (160--185\,K) for a field change of 0--5\,T around the
transition temperature, as evidenced by both the magnetic and
calorimetric measurements. Based on the analysis of low-temperature
heat capacity, it is found that the AFM--FM phase transition modifies
the electron density significantly, and the major contribution to
the entropy change comes from the electronic entropy change. |
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Keywords: | magnetic properties NaZnmagnetic properties NaZn$_{13}$-type compounds magnetic entropy change |
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