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| Hydrothermal Synthesis and Crystal Structure of a New Phosphonate： {[Cu（1,10-phen）]2-（H2O3PCH2C6H4C6H4CH2PO3H）2-（HO3PCH2C6H4C6H4CH2PO3H） }n | |
| 引用本文： | 傅瑞标,吴新涛,胡胜民,王龙胜. Hydrothermal Synthesis and Crystal Structure of a New Phosphonate： {[Cu（1,10-phen）]2-（H2O3PCH2C6H4C6H4CH2PO3H）2-（HO3PCH2C6H4C6H4CH2PO3H） }n[J]. 结构化学, 2004, 23(10): 1107-1110 |
| 作者姓名： | 傅瑞标 吴新涛 胡胜民 王龙胜 |
| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China |
| 基金项目： | This research was supported by grants from the State Key Laboratory of Structural Chemistry the National Ministry of Science and Technology of China (001CB1089) the Chinese Academy |
| 摘 要： | 1 INTRODUCTION Metal organophosphonates have attracted considerable attention for over three decades due to their potential or practical applications, include- ing ion exchanges[1, 2], molecular sensors[3] and optics[4, 5]. Recently, a number of porous m… |
| 关 键 词： | 合成 晶体结构 水热法 磷酸酯 铜 |
Hydrothermal Synthesis and Crystal Structure of a New Phosphonate:{[Cu(1,10-phen)]2-(H2O3PCH2C6H4C6H4CH2PO3H)2- (HO3PCH2C6H4C6H4CH2PO3H)}n |
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| Affiliation: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China |
| Abstract: | A new stepping chain {[Cu(1,10-phen)]2(H2O3PCH2C6H4C6H4CH2PO3H)2(HO3P- CH2C6H4C6H4CH2PO3H)}n 1 (C66H60Cu2N4O18P6) has been hydrothermally synthesized and charac- terized by single-crystal X-ray diffraction. It belongs to monoclinic, space group C2/c with a = 25.6114(4), b = 18.3781(2), c = 16.5180(3) ? b = 124.0610(10)? V = 6441.00(17) ?, Z = 4, Dc = 1.557 g/cm3, m(Mo-Ka) = 0.887 mm-1, F(000) = 3104, the final R = 0.0853 and wR = 0.1676 for 5585 independent reflections. |
| Keywords: | hydrothermal synthesis single crystal phosphonate |
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