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Palladium catalyzed atom-efficient cross-coupling reactions of triarylbismuths with aryl bromides |
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| Authors: | Maddali LN Rao Debasis Banerjee Deepak N Jadhav |
| Institution: | Department of Chemistry, Indian Institute of Technology, Kanpur 208 016, India |
| Abstract: | Aryl bromides (3 equiv) were coupled efficiently with triarylbismuths (1 equiv) in an atom-efficient way using the Pd(OAc)2/PPh3 catalytic system in the presence of K3PO4 as base in DMF at 90 °C, providing excellent yields of the cross-coupled biaryls in short reaction times. |
| Keywords: | Cross-coupling Triarylbismuth Aryl bromides Atom-efficient Palladium catalyzed |
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