Hydrosilylation and double silylation of carbonyl compounds with 1,1′-bis(dimethylsilyl)ferrocene using nickel- and platinum-catalysts |
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| Authors: | Young Kun Kong Jinsik Kim Seok-Bong Choi |
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| Institution: | a Department of Chemistry, Kyonggi University, Suwon, Kyonggido 440-760, Republic of Korea
b Center for Nanoscale Science and Engineering, North Dakota State University, Fargo, North Dakota 58105, USA |
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| Abstract: | A series of ferrocene-based organosilicon compounds have been prepared via hydrosilylation or double silylation of carbonyl compounds with 1,1′-bis(dimethylsilyl)ferrocene using (C2H4)Pt(PPh3)2 or Ni(PEt3)4 catalysts. In general, while the platinum catalyst (C2H4)Pt(PPh3)2 preferentially produced cyclic double-silylated products, the Ni(PEt3)4 catalyst led to the hydrosilylated ferrocene products from aldehydes or ketones. |
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| Keywords: | Hydrosilylation Dehydrogenative double silylation Catalyst Ferrocene Silane |
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