| 氮掺杂纳米管包覆金属钴催化苯甲醇和苯胺一步N-烷基化反应 |
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| 引用本文： | 李金磊,孟岩,王嘉,李福伟.氮掺杂纳米管包覆金属钴催化苯甲醇和苯胺一步N-烷基化反应[J].分子催化,2017,31(5):419-427. |
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| 作者姓名： | 李金磊 孟岩 王嘉 李福伟 |
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| 作者单位： | 1. 中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州730000;中国科学院大学,北京100049;2. 兰州大学核科学与技术学院,甘肃兰州,730000;3. 中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州,730000 |
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| 基金项目： | 国家自然科学基金（21373246，21503242，21773271） |
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| 摘 要： | 通过直接热解三聚氰胺、硝酸钴和葡萄糖混合物制备氮掺杂碳纳米管包覆金属钴催化剂(Co@NCNT).Co@NCNT具有较大的比表面积、均匀的氮分布以及包覆结构.在苯甲醇和苯胺一步法N-烷基化反应中Co@N CNT具有较高的催化活性,且循环4次反应活性没有明显的变化.控制实验和中毒实验表明金属Co和N对催化活性起着重要的作用,同时金属Co是中间产物N-苄叉苯胺加氢的主要活性位.
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| 关 键 词： | 氮掺杂碳纳米管 金属钴 N-烷基化 毒化实验 活性位 |
| 收稿时间： | 2017/7/3 0:00:00 |
| 修稿时间： | 2017/8/10 0:00:00 |
Nitrogen-doped Carbon Nanotube Encapsulated Cobalt Catalytic N-alkylation of Benzyl alcohol with Aniline |
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| LI Jin-lei,MENG Yan,WANG Jia and LI Fu-wei.Nitrogen-doped Carbon Nanotube Encapsulated Cobalt Catalytic N-alkylation of Benzyl alcohol with Aniline[J].Journal of Molecular Catalysis (China),2017,31(5):419-427. |
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| Authors: | LI Jin-lei MENG Yan WANG Jia and LI Fu-wei |
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| Institution: | State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;University of Chinese Academy of Sciences, Beijing 100049, China,Institute of nuclear science and technology, Lanzhou University, Lanzhou 730000, China,State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China and State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China |
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| Abstract: | Nitrogen doped carbon nanotube encapsulated cobalt (Co@NCNT) catalysts were prepared by direct pyrolysis the complex of melamine, cobalt nitrate and glucose. Co@NCNT possesses high surface area, homogeneous nitrogen dispersion and encapsulation structure. Co@NCNT shows efficient catalytic performance in the reaction of N-alkylation of aniline with benzyl alcohol, and the catalyst could reuse four times without obviously decrease in catalytic performance. Control experiments demonstrate that the cobalt and nitrogen played an important role in the catalytic performance, and poisoning tests illustrate that Cobalt was the active sites for hydrogenation of the intermediate N-benzylideneaniline. |
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| Keywords: | nitrogen-doped carbon nanotube metallic cobalt N-alkylation poisoning tests active sites |
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