| 具有二维网格结构的5-(4-硝基苯基)四唑-锌(Ⅱ)配合物 |
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| 引用本文： | 肖 杰,赵玉媛,王文祥,赵 红.具有二维网格结构的5-(4-硝基苯基)四唑-锌(Ⅱ)配合物[J].无机化学学报,2008,24(8):1347-1351. |
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| 作者姓名： | 肖 杰 赵玉媛 王文祥 赵 红 |
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| 作者单位： | 东南大学化学化工学院有序物质科学研究中心,南京,211189 |
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| 摘 要： | A zinc(Ⅱ) complex (5-(4-nitrophenyl)tetrazolato)2Zn]n was obtained by the hydrothermal treatment of ZnBr2 and NaN3 with 4-nitrobenzonitril in water at 120 ℃ in Pyrex tube. The crystal belongs to orthorhombic system with space group Pbcn, and a=1.040 7(5) nm, b=1.382 1(7) nm, c=2.435 1(13) nm, V=3.503(3) nm3, Z=8. This complex is a good blue fluorescent material in solid state at room temperature. CCDC: 684226.
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| 关 键 词： | 锌配合物 水热合成 晶体结构 荧光性质 |
A Novel 2D Zn-coordination Polymer Based on a 5-(4-nitrophenyl)-1H-tetrazole Ligand |
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| XIAO Jie,ZHAO Yu-Yuan,WANG Wen-Xiang and ZHAO Hong.A Novel 2D Zn-coordination Polymer Based on a 5-(4-nitrophenyl)-1H-tetrazole Ligand[J].Chinese Journal of Inorganic Chemistry,2008,24(8):1347-1351. |
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| Authors: | XIAO Jie ZHAO Yu-Yuan WANG Wen-Xiang and ZHAO Hong |
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| Institution: | Ordered Matter Science Research Center, School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189,Ordered Matter Science Research Center, School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189,Ordered Matter Science Research Center, School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189 and Ordered Matter Science Research Center, School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189 |
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| Abstract: | A zinc(Ⅱ) complex (5-(4-nitrophenyl)tetrazolato)2Zn]n was obtained by the hydrothermal treatment of ZnBr2 and NaN3 with 4-nitrobenzonitril in water at 120 ℃ in Pyrex tube. The crystal belongs to orthorhombic system with space group Pbcn, and a=1.0407(5) nm, b=1.382 1(7) nm, c=2.435 l(13) nm, V=3.503(3) nm3, Z=8.This complex is a good blue fluorescent material in solid state at room temperature. CCDC: 684226. |
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| Keywords: | zinc complex hydrothermal synthesis crystal structure fluorescence |
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