Analysis of the ν6(A″2) band of cyclopropane-d6 recorded under high resolution |
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| Authors: | AH Nielsen SJ Daunt GW Halsey |
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| Institution: | Molecular Spectroscopy Laboratory, Department of Physics and Astronomy, University of Tennessee, Knoxville, Tennessee 37916 USA |
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| Abstract: | The parallel band ν6(A″2) of C3D6 near 2336 cm?1 has been studied with high resolution (Δν = 0.020 – 0.024 cm?1) in the infrared. The band has been analyzed using standard techniques and the following parameters have been determined: B″ = 0.461388(20) cm?1, D″J = 3.83(17) × 10?7 cm?1, ν0 = 2336.764(2) cm?1, αB = (B″ ? B′) = 8.823(12) × 10?4 cm?1, βJ = (D″J ? D′J) = 0, and αC = (C″ ? C′) = 4.5(5) × 10?4 cm?1. |
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