The gas-phase molecular structure of CF3HgCH3 - an electron diffraction and microwave study |
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| Authors: | Horst Günther Heinz Oberhammer Reint Eujen |
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| Institution: | Institut für Physikalische und Theoretische Chemie der Universität TübingenW. Germany;Anorganische Chemie, Gesamthochschule Wuppertal, WuppertalW. Germany |
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| Abstract: | The molecular structure of CF3HgCH3 in the gas phase is determined by a joint analysis of electron diffraction and microwave data. The following geometric parameters (rav values) are derived: r(Hg—CH3) = 2.052(5) Å, r(Hg—CF3) = 2.116(4) Å. r(C-F) = 1.354(2) Å. r(C—H) = 1.079(14) Å, ∠.FCF = 105.7(0.2)° and ∠HCH = 107.0(1.5)°. Error limits are twice the standard deviations. |
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