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R-branch head of the ν3 band of CO2 at elevated temperatures
Authors:AS Pine  G Guelachvili
Institution:Lincoln Laboratory, Massachusetts Institute of Technology, Lexington, Massachusetts 02173 USA;Laboratoire d''Infrarouge, Associé au CNRS, Université de Paris XI, Bâtiment 350, 91405-Orsay, France
Abstract:The R-branch head of the 0001 ← 0000 band of 12C16O2 has been recorded with Doppler-limited resolution using a tunable laser difference-frequency spectrometer. J values to 140 were measured at temperatures to 985 K. The data have been combined with extremely precise transition frequencies for 0 ≤ J ≤ 76 measured with a Fourier transform interferometer to obtain an improved set of spectral constants for this ν3 band of CO2.
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