Rhenium-catalyzed deoxydehydration of renewable biomass using sacrificial alcohol as reductant期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Rhenium-catalyzed deoxydehydration of renewable biomass using sacrificial alcohol as reductant

Authors:	Justin Gossett Radhey Srivastava

Affiliation:	Department of Chemistry, University of Louisiana at Lafayette, Lafayette, LA 70504, USA

Abstract:	Catalytic deoxydehydration (DODH) of vicinal diols is studied. We find that NH₄ReO₄ (ammonium perrhenate, APR) catalyzes the DODH of glycols to alkenes by sacrificial alcohol (2,4-dimethyl-3-pentanol) at 140–165 °C. The product yields range from good to excellent and no isomers detected. The catalytic DODH reaction of glycols to alkene is of potential value for the production of chemicals and fuels from the renewable biomass-derived polyols. Download high-res image (24KB) Download full-size image

Keywords:	Deodehydration Vicinal diol Reductant Alkene Ammonium perrhenate 2,4-dimethyl-3-pentanol
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