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Three-component synthesis and optical properties of triarylpyridines containing a buta-1,3-diene-1,1,3-tricarbonitrile fragment
Authors:Ivan N Bardasov  Anastasiya U Alekseeva  Sergey S Chunikhin  Viktor A Tafeenko  Oleg V Ershov
Institution:1. Ulyanov Chuvash State University, Moskovsky pr. 15, Cheboksary 428015, Russia;2. Moscow State University, Vorob’evy gory 1, Moscow 119992, Russia
Abstract:The synthesis of triarylpyridine derivatives containing a buta-1,3-diene-1,1,3-tricarbonitrile fragment via the base-promoted reactions of aromatic aldehydes, 2-phenylacetophenone and a malononitrile dimer in the presence of an oxidant is described. The influence of aryl substituents in the 4-position on the optical properties is also reported.
Keywords:Pyridines  Three-component reaction  Malononitrile dimer  TCPy  Fluorescence
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