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2-(2-苯并咪唑)-6-甲基吡啶锌配合物的合成及发光性质
引用本文:潘荣楷,刘生桂,谭凤娇,苏仕铭.2-(2-苯并咪唑)-6-甲基吡啶锌配合物的合成及发光性质[J].化学研究与应用,2012(8):1259-1262.
作者姓名:潘荣楷  刘生桂  谭凤娇  苏仕铭
作者单位:湛江师范学院化学科学与技术学院
基金项目:湛江师范学院科研基金项目(L0810)资助
摘    要:合成了2-(2-苯并咪唑)-6-甲基吡啶及其锌配合物,通过元素分析、摩尔电导率、红外光谱和紫外光谱对产物进行了表征,并运用荧光光谱对配合物的发光性质进行了研究。结果表明,锌配合物在DMF溶液中的荧光最大发射波长为428nm,在固态下的荧光最大发射波长为448nm,均属于蓝光发射,具有作为蓝色发光材料的潜能。

关 键 词:2-(2-苯并咪唑)-6-甲基吡啶  锌配合物  发光性质

Synthesis and luminescent properties of 2-(2-benzimidazole)-6-methylpyridine zinc complex
PAN Rong-kai,LIU Sheng-gui,TAN Feng-jiao,SU Shi-ming.Synthesis and luminescent properties of 2-(2-benzimidazole)-6-methylpyridine zinc complex[J].Chemical Research and Application,2012(8):1259-1262.
Authors:PAN Rong-kai  LIU Sheng-gui  TAN Feng-jiao  SU Shi-ming
Institution:(Chemical Science and Technology School,Zhanjiang Normal University,Zhanjiang 524048,China)
Abstract:2-(2-benzimidazole)-6-methylpyridine and its zinc complex were synthesized.They were characterized by elemental analysis,molar conductivity,IR and UV-Vis spectroscopy.Their fluorescence properties were also studied by fluorescence spectrum.The results showed that the fluorescence maximum emission wavelengths of zinc complexes was at 428nm in DMF solution,while it was at 448nm in solid state.They belonged to blue-ray launch and had the potential for blue luminescence materials.
Keywords:2-(2-benzimidazole)-6-methylpyridine  Zinc complexes  luminescent properties
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