SYNTHESIS AND CRYSTAL STRUCTURE OF Mo_2OS(μ-S)_2[S_2CNC_4H_8]_2

Mo_2OS(μ-S)_2S_2CNC_4H_8]_2, Mr=612.61, triclinic, PI, a=8.666(2)(?), b=17.366(6)(?), c=6.708(1)(?), α=98.29(2)°, β=97.27(2)°, γ=79.36(2)°, V=976.5(5)(?)~3, Z=2, Dc=2.03g/cm~3, MoKα(λ=0.71069(?)), μ=19.75cm~(-1), F(000)=588, Final R=0.064, Rw=0.073 for 1517 unique intensity data (I>3σ(I)). The binuclear unit of Mo_2OS_3] has a new asymmetrically terminal coordinated configuration with Mo-Mo distance of 2.807(3)(?).