Prediction of wood property in Chinese Fir based on visible/near-infrared spectroscopy and least square-support vector machine |
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Authors: | Xiangrong Zhu Yang Shan Gaoyang Li Anmin Huang Zhuoyong Zhang |
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Institution: | aHunan Agricultural Product Processing Institute, Changsha 410125, PR China;bCollege of Chemistry and Chemical Engineering, Central South University, Changsha 410083, PR China;cResearch Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, PR China;dDepartment of Chemistry, Capital Normal University, Beijing 100048, PR China |
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Abstract: | A method for the quantification of density of Chinese Fir samples based on visible/near-infrared (vis–NIR) spectrometry and least squares-support vector machine (LS-SVM) was proposed. Sample set partitioning based on joint x–y distances (SPXY) algorithm was used for dividing calibration and prediction samples, it is of value for prediction of property involving complex matrices. A stepwise procedure is employed to select samples according to their differences in both x (instrumental responses) and y (predicted parameter) spaces. For comparison, the models were also constructed by Kennard–Stone method, as well as by using the duplex and random sampling methods for subset partitioning. The results revealed that the SPXY algorithm may be an advantageous alternative to the other three strategies. To validate the reliability of LS-SVM, comparisons were made among other modeling methods such as support vector machine (SVM) and partial least squares (PLS) regression. Satisfactory models were built using LS-SVM, with lower prediction errors and superior performance in relation to SVM and PLS. These results showed possibility of building robust models to quantify the density of Chinese Fir using near-infrared spectroscopy and LS-SVM combined SPXY algorithm as a nonlinear multivariate calibration procedure. |
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Keywords: | Wood density Visible/near-infrared spectrometry Least squares-support vector machines Partitioning based on joint x– y distances algorithm |
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