The quadrupole interaction of100Rh in various intermetallic compounds of palladium |
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Authors: | R Vianden E N Kaufmann R A Naumann G Schmidt |
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Institution: | (1) Bell Laboratories, 07974 Murray Hill, New Jersey, USA;(2) Department of Physics and Chemistry, Princeton University, 08540 Princeton, New Jersey, USA;(3) Present address: Institut für Strahlen-und Kernphysik, Universität Bonn, 5300 Bonn, West-Germany;(4) Present address: Institut für Experimentelle Kernphysik, Universität Karlsruhe, 7500 Karlsruhe, West-Germany |
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Abstract: | The nuclear quadrupole interaction of the 75 keV excited state of100Rh in the ordered intermetallic compounds PdHg, PdPb2 PdSb and PdTe was measured. Using an estimate for the nuclear quadrupole moment of the 75 keV state in100Rh and point ion lattice sums for the lattice electric field gradient (EFG) at the Rh site, the electronic contributionV
zz
el
to the total EFG was derived.V
zz
el
was found to be correlated with the average valence electron concentration in the compounds studied. In the case of PdPb2, the temperature dependence of the quadrupole interaction was also studied and found not to follow theT
3/2 rule which is observed in virtually all pure noncubic metals.Work partially supported by U.S. Department of Energy. |
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