Studies on fluorescent species of spiro-indolinonaphthooxazines and their fluorescence spectra |
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Authors: | M G Fan Y C Liang Y F Ming J X Chen T Ye Q Y Zhang B A Xu S Jin |
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Institution: | (1) Institute of Photographic Chemistry, Chinese Academy of Sciences, 100101 Beijing, P.R. China;(2) Institute of Chemistry, Chinese Academy of Sciences, 100080 Beijing, P.R. China;(3) Department of Chemistry, Peking University, 100871 Beijing, P.R. China |
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Abstract: | Photophysical behavior of spiro1,3,3-trimethylindolino-2,3′-naphtho2,1-b]-1,4-oxazine] (SP1) and spiro1,3,3,2′-tetramethylindolino-2,3′-naphtho2,1-b]-1,4-oxazine] (SP2) were studied. The fluorescent species and their spectra of SP1 and SP2 in polar solvents (acetonitrile and methanol) and non-polar solvent (cyclohexane) were investigated. The fluorescence decay
in polar solvents was studied by picosecond time-correlated single photon counting. In most cases, fluorescence decay obeyed
triexponential decay kinetics. The major fluorescent species is an excited intermediate which has similar conformation as
its precursor (1
SP
*) formed after the bond cleavage between spirocarbon and oxygen in oxazine ring. The effects of molecular structure and solvent
polarity on fluorescence spectra and fluorescence decay lifetime were studied. |
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Keywords: | |
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