A scale-dependent equation for solute transport in porous media

The governing equation describing solute transport in porous media is reformulated using standard volume averaging techniques. The alternative formulation is based on a modified definition of the deviation, which allows for variation of macroscopic velocity across the REV. The new equation contains additional scale-dependent terms which are functions of the size of the averaging volume (REV). This result indicates that the scale-dependent nature of the dispersion phenomenon is inherent even at the scale of the REV.