Polyhydroxylated indolizidine alkaloids—synthesis of dideoxycastanospermine |
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Authors: | Ari MP Koskinen Oili A Kallatsa |
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Institution: | a Laboratory of Organic Chemistry, Helsinki University of Technology, PO Box 6100, FIN-02015 HUT, Finland b Department of Chemistry, University of Oulu, FIN-90570 Oulu, Finland c X-ray Structure, Department of Chemistry, University of Jyväskylä, FIN-90570 Jyväskylä, Finland |
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Abstract: | The key transformation developed in this work is the anti-Kishi selective dihydroxylation, which proceeds by way of intramolecular participation of the nitrogen protecting group to furnish the desired stereochemistry required for castanospermine like structures. In this paper, we completed a first synthesis of a novel dideoxycastanospermine 6. |
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