Synthesis, crystal structure and optical properties of the new lead fluoride borate—Pb2BO3F |
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| Authors: | Wenwu Zhao Shilie Pan Jian Han Jiyong Yao Yun Yang Junjie Li Min Zhang Lian Han Zhang Yin Hang |
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| Institution: | aXinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, 40-1 South Beijing Road, Urumqi 830011, China;bGraduate School of the Chinese Academy of Sciences, Beijing 100049, China;cTechnical Institute of Physics & Chemistry, Beijing 100049, China;dShanghai Institute of Optics & Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China |
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| Abstract: | A new compound, Pb2BO3F, has been grown by high temperature solution method from the PbO–PbF2–B2O3 system for the first time. The crystal structure of this compound has been identified by single crystal X-ray diffraction analysis. It crystallizes in the hexagonal system, space group P63/m (No. 176) with unit-cell parameters a=7.2460(3) Å, c=14.5521(17) Å, Z=6, V=661.69(9) Å3. Its structure was solved by the direct methods and refined to R1=0.0163 and wR2=0.0367. The structure of Pb2BO3F consists of the distorted PbO3F2 groups and BO3 triangles, which are all symmetric with each other in the gestalt structure to the extent that the Pb2BO3F compound crystallizes in the symmetric space group. The powder X-ray diffraction pattern of the Pb2BO3F has been measured. The BO3 functional groups presented in the sample were identified by FTIR spectrum. The DTA curve of Pb2BO3F suggests that Pb2BO3F melts congruently at 448 °C. |
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| Keywords: | Pb2BO3F Synthesis Crystal structure Borate |
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