| Transfer Hydrogenation of C= C Double Bonds Catalyzed by Ruthenium Amido-Complexes: Scopes, Limitation and Enantioselectivity |
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| 引用本文： | XUE,Dong CHENG,Ying-Chun CUI,Xin WANG,Qi-Wei ZHU,Jin DENG,Jin-Gen. Transfer Hydrogenation of C= C Double Bonds Catalyzed by Ruthenium Amido-Complexes: Scopes, Limitation and Enantioselectivity[J]. 有机化学, 2004, 24(Z1): 53 |
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| 作者姓名： | XUE Dong CHENG Ying-Chun CUI Xin WANG Qi-Wei ZHU Jin DENG Jin-Gen |
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| 作者单位： | XUE,Dong（Key Laboratory of Asymmetric Synthesis & Chirotechnology of Sichuan Province and Union Laboratory of Asymmetric Synthesis, Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041） CHENG,Ying-Chun（Key Laboratory of Asymmetric Synthesis & Chirotechnology of Sichuan Province and Union Laboratory of Asymmetric Synthesis, Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041） CUI,Xin（Key Laboratory of Asymmetric Synthesis & Chirotechnology of Sichuan Province and Union Laboratory of Asymmetric Synthesis, Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041） WANG,Qi-Wei（Key Laboratory of Asymmetric Synthesis & Chirotechnology of Sichuan Province and Union Laboratory of Asymmetric Synthesis, Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041） ZHU,Jin（Key Laboratory of Asymmetric Synthesis & Chirotechnology of Sichuan Province and Union Laboratory of Asymmetric Synthesis, Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041） DENG,Jin-Gen（Key Laboratory of Asymmetric Synthesis & Chirotechnology of Sichuan Province and Union Laboratory of Asymmetric Synthesis, Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041） |
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| 摘 要： | The reduction of C = C double bonds is one of the most fundamental synthetic transformations and plays a key role in the manufacturing of a wide variety of bulk and fine chemicals. Hydrogenation of olefinic substrates can be achieved readily with molecular hydrogen in many cases, but transfer hydrogenation methods using suitable donor molecules such as formic acid or alcohols are receiving increasing attention as possible synthetic alternatives because it requires no special equipment and avoids the handling of potentially hazardous gaseous hydrogen.
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Transfer Hydrogenation of C= C Double Bonds Catalyzed by Ruthenium Amido-Complexes:Scopes, Limitation and Enantioselectivity |
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| XUE,Dong,CHENG,Ying-Chun,CUI,Xin,WANG,Qi-Wei,ZHU,Jin,DENG,Jin-Gen. Transfer Hydrogenation of C= C Double Bonds Catalyzed by Ruthenium Amido-Complexes:Scopes, Limitation and Enantioselectivity[J]. Chinese Journal of Organic Chemistry, 2004, 24(Z1): 53 |
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| Authors: | XUE Dong CHENG Ying-Chun CUI Xin WANG Qi-Wei ZHU Jin DENG Jin-Gen |
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| Abstract: | The reduction of C = C double bonds is one of the most fundamental synthetic transformations and plays a key role in the manufacturing of a wide variety of bulk and fine chemicals. Hydrogenation of olefinic substrates can be achieved readily with molecular hydrogen in many cases, but transfer hydrogenation methods using suitable donor molecules such as formic acid or alcohols are receiving increasing attention as possible synthetic alternatives because it requires no special equipment and avoids the handling of potentially hazardous gaseous hydrogen. |
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