Structural Elucidation of {[(CH3)2SnCl2·H2O]2·18-crown-6}
n
and its Hydrogen Bonding in Solution by HMBC Spectroscopy |
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| Authors: | Mostafa M Amini Amirreza Azadmher Hamid Reza Bijanzadeh Nasser Hadipour |
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| Institution: | (1) Department of chemistry, Shahid Beheshti University, 1983963113, Tehran, Iran;(2) Department of chemistry, Trabit Modaress University, Tehran, Iran |
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| Abstract: | Behavior of {(CH3)2SnCl2·H2O]2·18-crown-6}n in solution have been investigated by HMBC NMR. The results show that coordination of water to tin containing species and
its hydrogen bonding to crown ether remains intact in non-coordinating solvent in contrast to coordinating solvent. H-NMR
reveals that the chemical shift of water in complex varies by solvent of crystallization. |
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| Keywords: | 2-D HMBC NMR crown ether dimethyltin dichloride hydrogen bonding |
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