Reactions of azoles with tetrachloro-1,2-difluoroethane and 1,2-dichlorodifluoroethylene |
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Authors: | K I Petko T M Sokolenko S Yu Kot T A Kasyanchuk L M Yagupol’skii |
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Institution: | (1) Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, 02094, Ukraine |
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Abstract: | Tetrachloro-1,2-difluoroethane reacted with pyrazole and imidazole sodium salts to give mixtures of the corresponding N-(1,2,2-trichloro-1,2-difluoroethyl) derivatives and (E)-1,2-difluoro-1,2-dihetarylethenes. (E)-1,2-Difluoro-1,2-di(3,5-dimethyl-1H-pyrazol-1yl)ethene was also obtained as a result of replacement of chlorine atoms in 1,2-dichloro-1,2-difluoroethene. Analogous
reaction with more nucleophilic imidazole involved replacement of not only chlorine but also fluorine atoms in 1,2-dichloro-1,2-difluoroethene,
yielding tetraimidazolyl-substituted ethylene. |
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