Extending Pummerer reaction chemistry. Synthesis studies in the phakellin alkaloid area |
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| Authors: | Feldman Ken S Skoumbourdis Amanda P Fodor Matthew D |
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| Affiliation: | Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, USA. ksf@chem.psu.edu |
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| Abstract: | ![]()
The syntheses of (+/-)-dibromophakellstatin and, from this species, (+/-)-dibromophakellin are described. Oxidative cyclization of a phenylthiolated dihydrooroidin derivative triggered by a Pummerer reaction constitutes the key step in this biomimetic approach to this family of marine alkaloids. |
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