| Synthesis of Fullerene-end Functionalized Poly（methyl methacrylate） via Reverse Atom Transfer Radical Polymerization |
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| 引用本文： | 郭崇东 滕文锐 吴惠霞 沈建中 邓啸旻 蔡瑞芳. Synthesis of Fullerene-end Functionalized Poly（methyl methacrylate） via Reverse Atom Transfer Radical Polymerization[J]. 中国化学, 2005, 23(8): 1113-1119. DOI: 10.1002/cjoc.200591113 |
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| 作者姓名： | 郭崇东 滕文锐 吴惠霞 沈建中 邓啸旻 蔡瑞芳 |
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| 作者单位： | [1]Department of Chemistry, Fudan University, Shanghai 200433, China [2]Department of Mechanics and Electronics, Chemical Engineering College, Zhengzhou, Henan 450042, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （No. 20271013）. |
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| 摘 要： | The use of the reverse atom transfer radical polymerization （RATRP） to end-functionalize poly（methyl methacrylate） （PMMA） with fullerenes, e.g. C60 and C70 was described in this paper. The Cl-terrninated PMMA was prepared via RATRP with designed molecular weight and narrow molecular weight distributions, and then directly used to react with fullerenes to produce C60（C70） terminated PMMA polymers in the presence of CuBr/Cu/bipy or FeCl2/bipy catalysts. The resultant polymers exhibit good solubility in some common organic solvents, e.g. THF, CHCl3 and toluene, and were well structurally characterized by a variety of physical techniques.
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| 关 键 词： | 合成 球壳状碳分子 聚（甲基丙烯酸甲酯） 晶体结构 原子转移游离基聚合 |
| 收稿时间： | 2004-10-25 |
| 修稿时间： | 2004-10-25 |
Synthesis of Fullerene‐end Functionalized Poly(methyl methacrylate) via Reverse Atom Transfer Radical Polymerization |
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| Guo ChongDong;Teng WenRui;Wu HuiXia;Shen JianZhong;Deng XiaoMin;Cai RuiFang. Synthesis of Fullerene‐end Functionalized Poly(methyl methacrylate) via Reverse Atom Transfer Radical Polymerization[J]. Chinese Journal of Chemistry, 2005, 23(8): 1113-1119. DOI: 10.1002/cjoc.200591113 |
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| Authors: | Guo ChongDong Teng WenRui Wu HuiXia Shen JianZhong Deng XiaoMin Cai RuiFang |
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| Abstract: | The use of the reverse atom transfer radical polymerization (RATRP) to end‐functionalize poly(methyl methacrylate) (PMMA) with fullerenes, e.g. C60 and C70 was described in this paper. The Cl‐terminated PMMA was prepared via RATRP with designed molecular weight and narrow molecular weight distributions, and then directly used to react with fullerenes to produce C60(C70) terminated PMMA polymers in the presence of CuBr/Cu/bipy or FeCl2/bipy catalysts. The resultant polymers exhibit good solubility in some common organic solvents, e.g. THF, CHCl3 and toluene, and were well structurally characterized by a variety of physical techniques. |
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| Keywords: | fullerene PMMA synthesis structural characterization atom transfer radical polymerization |
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