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Influence of a Solvent on the Quantum Yield and Duration of the Fluorescence of Tetraazoporphin
Authors:I.?K.?Shushkevich  author-information"  >  author-information__contact u-icon-before"  >  mailto:llum@imaph.bas-net.by"   title="  llum@imaph.bas-net.by"   itemprop="  email"   data-track="  click"   data-track-action="  Email author"   data-track-label="  "  >Email author,P.?P.?Pershukevich,A.?P.?Stupak,K.?N.?Solov'ev
Affiliation:(1) Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, 70 Nezavisimost' Ave., Minsk, 220072, Belarus
Abstract:In view of the discrepancies between the values available in the literature for the photophysical parameters of tetraazaporphin in solutions, we measured its quantum yield and duration of fluorescence in a number of solvents. It has been found that alcohols (isobutanol and isopropanol) quench the fluorescence appreciably. For a solution in toluene — a stable chemically inactive and low-polar solvent — the measured quantum yield of the fluorescence of tetraazaporphin is equal to 0.180 ± 0.015 and its duration is 3.4 ± 0.1 nsec. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 5, pp. 697–699, September–October, 2005.
Keywords:tetraazaporphin  quantum yield of fluorescence  fluorescence duration
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