Synthesis and characterization of binuclear palladium(II) and platinum(II) complexes with a bridging hydroxypyridinate ligand |
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| Authors: | Vimal K Jain |
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| Institution: | (1) Chemistry Division, Bhabha Atomic Research Centre, 400 085 Trombay, Mumbai, India |
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| Abstract: | Summary Binuclear PdII and PtII complexes of the type M2Cl2( -Opy)2(PR3)2] M = Pd or Pt; Opy = 2-OC5H4N (2-hydroxypyridinate ion); PR3 = PEt3, Pn-Bu3, PMe2Ph or PMePh2] were synthesized and characterized by elemental analysis, 1H- and 31P-n.m.r. spectroscopies. The Pd complexes exist in the sym trans form, whereas the corresponding Pt complexes were generated as different isomers. |
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