| 功能化程序对笼形聚偕氨肟树脂吸附和吸留性质的影响 |
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| 引用本文： | 吴锦远,杨超雄.功能化程序对笼形聚偕氨肟树脂吸附和吸留性质的影响[J].广州化学,1994(Z1). |
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| 作者姓名： | 吴锦远 杨超雄 |
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| 作者单位： | 中国科学院广州化学研究所!广州 |
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| 摘 要： | 聚丙烯颗粒在水溶液中与丙烯腈和二乙烯基苯反应,得接枝交联产物（Ⅰ）。Ⅰ被氨肟化再经成笼反应．得笼形聚偕氨肟树脂（Ⅱ）。笼内仅吸留易于除去的溶剂丙酮。若Ⅰ成笼后再氨肟化,所得吸收剂（Ⅲ）将吸留大量的羟胺,它缓慢地释放出来,干扰吸收剂对酸、碱离子或分子吸附容量的测定。Ⅱ对一些离子例如Hg2+和MnO4-的吸附能力与Ⅲ不同,被认为是两者的网络结构不同所致。
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| 关 键 词： | 笼形树脂 聚偕氨肟 功能化 吸附作用 吸留作用 |
Effect of functionalization procedure on the adsorption and occlusion properties of polyamidoxime adsorbent |
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| Wu Jinyuan, Yang Chaoxiong.Effect of functionalization procedure on the adsorption and occlusion properties of polyamidoxime adsorbent[J].Guangzhou Chemistry,1994(Z1). |
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| Authors: | Wu Jinyuan Yang Chaoxiong |
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| Abstract: | Grafted and cross1inked product (Ⅰ) was obtained by the reaction of polypropylene particles with aerylonitrile and divinylbenzene in aqueous solution. Ⅰ was subjected to amidoximation and then cage-formation to give a " cage" polyamidoxime adsorbent (Ⅱ).The solvent acetone is occluded into the cage alone, it can be removed easily. If Ⅰ has been formed in cage -shape and follows by amidoximation, the adsorbent (Ⅲ) obtained would occludes a great quantity of hydroxylamine, it releases gradually and interferes with the determinations of adsorption Capacity for acids, bases, and other ions or molecules. The adsorption abi1itY of Ⅱ for some ions such as mercury (Ⅱ) and permanganate differs from Ⅲowing to the difference in their network strructure. |
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| Keywords: | cage adsorbent polyamidoxime functionalization adsorption occlusion |
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