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Mechanochemistry of the 5f-element compounds |
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| Authors: | P. Kovacheva N. Minkova D. Todorovsky D. Radev |
| Affiliation: | (1) Faculty of Chemistry, University of Sofia, 1, J. Bourchier Blvd., Sofia, 1164, Bulgaria;(2) Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Acad. Bonchev Str., bl.11, Sofia, 1113, Bulgaria |
| Abstract: | The effect of the mechanical treatment of UO2(CH3COO)2·2H2O in a planetary ball mill in air or as a suspension in toluene or benzene on its crystal structure and coordination mode has been studied. No significant changes in the crystal structure are observed. IR-spectroscopy results suggest that in the part of the mechanoactivated material the bidentate bonding of the CH3COO− is transformed in monodentate one. The newformed species is soluble in non-polar solvents. |
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