Effect of carbon dioxide on the catalytic oxidation of ethylene over silver. Kinetic reaction model accounting for the modification of catalyst surface by carbonate groups |
| |
| Authors: | D A Bulushev and A V Khasin |
| |
| Institution: | (1) Institute of Catalysis, 630090 Novosibirsk, USSR |
| |
| Abstract: | Changes in the character of catalytic oxidation of ethylene over silver upon increasing pressure of reaction mixture, reflected in increased ethylene oxide selectivity, are due to the modifying effect of suface carbonate groups. A kinetic reaction model is suggested based on the individual investigations of reaction steps.
                        ,   ,    .    , .
|
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
