| Chemical preparation and investigation of Fe-P-B ultrafine amorphous alloy particles |
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| 作者姓名： | 胡征 吴勇 范以宁 颜其洁 陈懿 |
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| 作者单位： | Department of Chemistry，Nanjing University，Nanjing 210093，China，Department of Chemistry，Nanjing University，Nanjing 210093，China，Department of Chemistry，Nanjing University，Nanjing 210093，China，Department of Chemistry，Nanjing University，Nanjing 210093，China，Department of Chemistry，Nanjing University，Nanjing 210093，China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China，85-06 NMS |
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| 摘 要： | A series of Fe-P-B ultrafine amorphous alloy particles has been prepared by the chemical reduction method The composition and size of the particles have been effectively adjusted.Mossbauer spectroscopy in addition to sonic other techniques has been used to investigate the reaction process,the factors that influence the preparation,the crystallization of the particles,and the interactions between the components within them.The results indicate that the co-deposition of iron,phosphorus and boron atoms in the solution at room temperature forms Fe-P-B amorphous alloy particles,and a preferential bonding of Fe-P bond to Fe-B one exists in the particles.
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| 收稿时间： | 22 August 1996 |
Chemical preparation and investigation of Fe-P-B ultrafine amorphous alloy particles |
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| Zheng Hu,Yong Wu,Yining Fan,Qijie Yan,Yi Chen.Chemical preparation and investigation of Fe-P-B ultrafine amorphous alloy particles[J].Science in China(Chemistry),1997,40(3):261-269. |
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| Authors: | Zheng Hu Yong Wu Yining Fan Qijie Yan Yi Chen |
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| Institution: | (1) Department of Chemistry, Nanjing University, 210093 Nanjing, China |
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| Abstract: | A series of Fe-P-B ultrafine amorphous alloy particles has been prepared by the chemical reduction method The composition and size of the particles have been effectively adjusted.Mossbauer spectroscopy in addition to sonic other techniques has been used to investigate the reaction process,the factors that influence the preparation,the crystallization of the particles,and the interactions between the components within them.The results indicate that the co-deposition of iron,phosphorus and boron atoms in the solution at room temperature forms Fe-P-B amorphous alloy particles,and a preferential bonding of Fe-P bond to Fe-B one exists in the particles. |
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| Keywords: | amorphous alloy ultrafine particles chemical preparation Mossbauer spectroscopy |
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