| 醇类在苯及对二甲苯中过量焓预测 |
| |
| 引用本文： | 裘利言,姚惟馨.醇类在苯及对二甲苯中过量焓预测[J].化学研究与应用,1996,8(2):232-235. |
| |
| 作者姓名： | 裘利言 姚惟馨 |
| |
| 作者单位： | 南京化工学院应用化学系 |
| |
| 摘 要： | 醇类在苯及对二甲苯中过量焓预测裘利言，姚惟馨（南京化工学院应用化学系南京２１０００９）关键词醇，芳烃，缔合，过量焓含醇体系的热力学性质研究近来十分活跃。通常文献所报道的醇－芳烃体系中醇的摩尔分数ｘ＿Ａ在０．１～０．９，而对于极稀溶液区有关报道很少。这...
|
| 关 键 词： | 醇 芳烃 缔合 焓 苯 |
PREDICTION OF EXCESS ENTHALPIES OF ALCOHOL AND BENZENE OR P-XYLENE |
| |
| Qiu Liyan,Yao Weixin.PREDICTION OF EXCESS ENTHALPIES OF ALCOHOL AND BENZENE OR P-XYLENE[J].Chemical Research and Application,1996,8(2):232-235. |
| |
| Authors: | Qiu Liyan Yao Weixin |
| |
| Abstract: | With association equilibrium constants k_A from freezing point depression and Wiehe-Bagley model the excess enthaplies for alcohol and benzene or p-xylene are predicted. The enthalpy of hydrogen bond h_A increases as the carbon numbers n_A of alcohols increase and is a constant after propanol. For the same alcohol h_A is larger in benzene than in p-xylene. The change of molar enthalpies at infinite dilution has similar properdes to h_A There is a linear relationship between ln k_A and In h_A. |
| |
| Keywords: | alcohols aromatic hydrocarbon enthalpy |
| 本文献已被 CNKI 维普 等数据库收录！ |
