The diverse behaviour of the P–Cl bonds in the spiro–cis–ansa spermidine derivative cyclotriphosphazene towards mono-functional nucleophilic reagents |
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Authors: | Hanife biolu Baak Temur lker Ün |
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Institution: | aDepartment of Chemistry, Gebze Institute of Technology, Gebze 41400, Kocaeli, Turkey |
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Abstract: | A number of new spiro–ansa spermidine derivative cyclotriphosphazenes (2–10) is synthesized in order to provide insight into the reaction mechanism for nucleophilic substitution. The structures of the compounds were determined by elemental analysis, mass (MS), 1H, 19F (for 9) and 31P NMR spectroscopies. Compounds (2–8) and 9, 10 can be formed by a proton abstraction–chloride elimination and both the and reaction mechanisms, respectively. |
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Keywords: | Cyclotriphosphazene Nucleophilic substitution Phosphazene 31P NMR Spermidine Reaction mechanism 19F NMR |
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