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The hydrogenolysis of C60 and C70
Authors:Toshihiko Osaki   Toshiyuki Tanaka  Yutaka Tai
Affiliation:(1) National Institute of Advanced Industrial Science and Technology (AIST), 2266-98 Anagahora, Shimoshidami, Moriyama-ku, Nagoya 463-8560, Japan;(2) Daido Institute of Technology, Takiharu-cho, Minami-ku, Nagoya 457-8530, Japan
Abstract:
Temperature-programmed reaction (TPR) of C60 and C70 with H2 was carried out on nickel in order to investigate the thermal stability of the fullerenes in the catalytic hydrogenation. The TPR profiles showed two methanation peaks and the corresponding weight decrease above 420°C, indicating the hydrogenolysis to CH4. This revised version was published online in June 2006 with corrections to the Cover Date.
Keywords:fullerene  hydrogenolysis  C60  C70
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