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| 环己烷甲酸根桥联的二维锰配合物的合成与表征 | |
| 引用本文： | 王 君,马运声,袁荣鑫,谢吉民.环己烷甲酸根桥联的二维锰配合物的合成与表征[J].无机化学学报,2009,25(4):742-745. |
| 作者姓名： | 王 君 马运声 袁荣鑫 谢吉民 |
| 作者单位： | 1. 江苏大学化学化工学院,镇江,212013;常熟理工学院化学与材料工程系,江苏省新型功能材料重点建设实验室,常熟,215500 2. 常熟理工学院化学与材料工程系,江苏省新型功能材料重点建设实验室,常熟,215500 3. 江苏大学化学化工学院,镇江,212013 |
| 基金项目： | 江苏省自然科学基金，江苏省教育厅重大基金 |
| 摘 要： | Complex Mn2(C6H11CO2)3(4,4′-bipy)2(H2O)2]ClO4 (C6H11CO2H=cyclohexanecarboxylic acid) was synthesized by reaction of Mn(ClO4)2·6H2O, C6H11CO2Na and 4,4′-bipy in methanol. The title complex crystallizes in triclinic space group P1, with a=1.008 8(2) nm, b=1.086 3(1) nm, c=1.164 9(3) nm, α=63.016(3)°, β=81.998(4)°, γ=88.604(1)°, V=1.125 4(4) nm3, Z=1. There are two types of Mn atoms in the structure with each in octahedral geometry. Mn1 and Mn2 are bridged by cyclohexanecarboxylate ligands into a chain and the chains are further linked together by 4,4′-bipy into a 2D plane. CCDC: 692247. |
| 关 键 词： | 合成 表征 锰 环己烷甲酸根 |
Synthesis and Characterization of A Two-Dimensional Mn Complex Bridged by Cyclohexanecarboxylate |
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| WANG Jun,MA Yun-Sheng,YUAN Rong-Xin and XIE Ji-Min.Synthesis and Characterization of A Two-Dimensional Mn Complex Bridged by Cyclohexanecarboxylate[J].Chinese Journal of Inorganic Chemistry,2009,25(4):742-745. | |
| Authors: | WANG Jun MA Yun-Sheng YUAN Rong-Xin and XIE Ji-Min |
| Institution: | School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013; Department of Chemistry & Materials Engineering, Jiangsu Key Laboratory of Advanced Functional Materials, Changshu Institute of Technology, Changshu, Jiangsu 2155,Department of Chemistry & Materials Engineering, Jiangsu Key Laboratory of Advanced Functional Materials, Changshu Institute of Technology, Changshu, Jiangsu 215500,Department of Chemistry & Materials Engineering, Jiangsu Key Laboratory of Advanced Functional Materials, Changshu Institute of Technology, Changshu, Jiangsu 215500 and School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013 |
| Abstract: | ComplexMn2(C6H11CO2)3(4,4'-bipy)2(H2O)2]ClO4(C6H11CO2H=cyclohexanecarboxylic acid)was synthesized group P1,with a=1.008 8(2)nm,b=1.086 3(1)nm,c=1.1649(3)nm,α=63.016(3)°,β=81.998(4)°,γ=88.604(1)°,V=1.125 4(4)nm3,Z=1.There are two types of Mn atoms in the structure with each in octahedral geometry.Mnl and Mn2 are bridged by cyelohexanecarboxylate ligands into a chain and the chains are further linked together bv 4.4'-bipy into a 2D plane.CCDC:692247. |
| Keywords: | synthesis characterization manganese cyclohexanecarboxylate |
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