A study of final state structure in the x-pe spectra of the rare earth oxides,Part III: Ionisation of a 4d electron |
| |
| Authors: | AF Orchard G Thornton |
| |
| Institution: | Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QR Great Britain |
| |
| Abstract: | Metal 4d photoelectron spectra of the lanthanoid oxides Ln2O3 are reported. The 4d signals are complex, showing subsidiary structure due both to electrostatic interactions within the 4d94?n configurations and to accompanying O 2p → Ln 4? charge-transfer excitations (shake-up). The effects of electrostatic coupling, including configuration interaction in the final state, are analysed in terms of a simple model. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
