| Preparation, Electrochemical Property and Application in Bulk-modified Electrode of Dawson-type Phosphomolybdate-doped Polypyrrole Composite Nanoparticles |
| |
| 作者姓名： | WANG Xiu-li ZHAO Hai-yan WANG Yi-fei |
| |
| 作者单位： | WANG Xiu-li **，ZHAO Hai-yan and WANG Yi-feiFaculty of Chemistry and Chemical Engineering，Bohai University，Jinzhou 121000，P. R. China |
| |
| 基金项目： | 辽宁省自然科学基金，辽宁省教育厅资助项目 |
| |
| 摘 要： | IntroductionPolyoxometalates(POMs)have attracted much at-tention in catalysis,medicine,bioanalysis and materialsciences due to their chemical,structural and electro-nic versatility in recent years1—3].One of the most im-portant properties of POMs is the…
|
| 关 键 词： | 道森型磷钼酸盐 聚吡咯 纳米化合物 填充改性 碳糊电极 电催化作用 |
| 文章编号： | 1005-9040（2006）-05-556-04 |
| 收稿时间： | 2006-05-15 |
Preparation, Electrochemical Property and Application in Bulk-modified Electrode of Dawson-type Phosphomolybdate-doped Polypyrrole Composite Nanoparticles |
| |
| WANG Xiu-li ZHAO Hai-yan WANG Yi-fei.Preparation, Electrochemical Property and Application in Bulk-modified Electrode of Dawson-type Phosphomolybdate-doped Polypyrrole Composite Nanoparticles[J].Chemical Research in Chinese University,2006,22(5):556-559. |
| |
| Authors: | Xiu-li WANG Hai-yan ZHAO Yi-fei WANG |
| |
| Institution: | aFaculty of Chemistry and Chemical Engineering, Bohai University, Jinzhou 121000, P. R. China |
| |
| Abstract: | A kind of inorganic-organic hybrid semiconductor composite nanoparticles: Dawson-type phosphomolybdate-doped polypyrrole(P_2Mo_ 18-PPy) was designed and prepared using microemulsion oxidation-polymerization at room temperature and characterized by TEM and IR. The P_2Mo_ 18-PPy was used as a bulk-modifier to fabricate a chemically modified carbon paste electrode(CPE) by direct mixing, which represents the example of polyoxometalates(POMs)-doped semiconductor polymer nanoparticles modified electrode. Both the advantage of POMs-doped polymer and the surface-renewal property of the CPE were fully utilized. The electrochemical behavior of the P_2Mo_ 18-PPy bulk-modified CPE(P_2Mo_ 18-PPy-CPE) was investigated with cyclic voltammetry. Three couples of reversible redox peaks were observed in the range from 800 to 0 mV, which corresponded to the reduction and oxidation through two-, four- and six-electron processes, respectively. The P_2Mo_ 18-PPy-CPE showed a high electrocatalytic activity for the reduction of nitrite, which expanded the application of POMs-doped semiconductor polymer nanoparticles. |
| |
| Keywords: | Dawson-type phosphomolybdate Polypyrrole Composite nanoparticles Bulk-modified Carbon paste electrode Electrocatalysis |
| 本文献已被 CNKI 维普 万方数据 ScienceDirect 等数据库收录！ |
